Wake up on a hilltop overlooking the kingdom of truffles and enjoy breakfast on the hotel's splendid terrace. Take a hike along the truffle route, to learn the art of 'hunting' this precious subterranean mushroom also called the 'black gold.' Enjoy a truffle tasting paired with local red wine, and continue hiking to Groznjan, a walled Renaissance town perched on another hill. Wander around this enchanting town of artists, known for its art studios, galleries, and gorgeous views. Return to Motovun to unwind at the hotel's swimming pool and spa.

Leave the Adriatic today and head into the Alps, leaving Croatia behind and entering Slovenia. The first stop is in the Slovenian karst region - the Skocjan Caves, a UNESCO World Heritage Site where you take a 2-hour underground walk. Continue to Ljubljana, Slovenia's charming capital that has recently become one of the hippest cities in Europe. Wander around the small, green city center along the banks of Ljubljanica River, exploring the highlights, and travel on to Lake Bled, a picturesque alpine lake and the location of tonight's hotel.

Today take in the picture-postcard tranquility of Lake Bled, with the bell tower of a medieval church rising from a tiny islet in the midst of the lake, guarded by a clifftop castle. Embark on a rewarding hike through Blejski Vintgar Gorge, walking above crystal-clear Radovna Stream on wooden planks over the whirlpools. Transfer to Bohinj Lake, Bled's wild brother, to hike on a soft forest trail by the lake. Return to Bled, known for its healing thermal waters; enjoy a spa treatment or massage before dinner.

Take a ride around the Julian Alps en route to the emerald-green Soca River Valley. Pass the village of Kranjska Gora, before heading up to the Vrsic pass (5,290'), once the border line between Italy and the Austro-Hungarian Empire. Take in breathtaking views and continue the winding drive to the spring of the Soca River, hike down into its magnificent valley and visit a museum dedicated to a WWI battle that took place in the valley. Finish the day with a culinary extravaganza prepared by Slovenia's best chef, Ana Ros.

Enjoy a delicious breakfast and a brief tour of chef Ana's herb garden. Say goodbye to Slovenia and enter the Italian province of Friuli-Venezia-Giulia. Hike up to the top of the scenic Montemaggiore for its famous views; on a clear day, see the blue Adriatic, the Julian Alps, and the Dolomites in the distance. In the afternoon, take a short drive to Collio wine country, a hilly vineyard area spreading over Slovenia and Italy. Visit the local wineries to sample the 'big reds,' and Friuli's exquisite wine grape called ribolla.

Travel west to the Italian region of Veneto, along the way visiting the historical city of Vicenza and its lovely countryside, famed for the Renaissance villas built by the great architect Andrea Palladio. The tour ends at the airport in Venice in the late afternoon, where you depart on homeward-bound flights.